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May 21, 2013
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Sizzle From The Sun


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"Beyond the Molecular Frontier: Challenges for Chemistry and
Chemical Engineering"
- National Academy of Sciences 2003 report (see chapter 10 on solar energy)

Cornell University study: The potential of renewable energy



   06.12.03
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Soaking up the summer sun could mean a good source of power that lowers your fuel bills. But today’s solar cells aren’t cheap or efficient enough for widespread use. As this ScienCentral News video reports, some researchers in nanotechnology are hard at work trying to change that.

Nanoscale Cells, Mega Energy

According to the National Renewable Energy Laboratory, the U.S. Department of Energy’s center of solar-power research, about every 40 minutes enough of the sun’s energy reaches the earth to meet everyone’s needs for electric power for an entire year. The worldwide solar power industry is growing rapidly, but it’s still relatively small compared to oil, gas and coal. If the industry is to keep expanding, solar cells must become less expensive and more efficient.

At the University of California Berkeley and the Lawrence Berkeley National Laboratory, chemist Paul Alivisatos is best known for his pioneering work with quantum dots. Under ultraviolet light, these extremely tiny particles of semi-conducting materials emit an enormous spectrum of very bright colors. In biology, some researchers have been using quantum dots to illuminate living cells’ activities for the first time.





But Alivisatos also is interested in another use for quantum dots, as part of solar cells. When he read a report from the National Academy of Sciences on alternatives to fossil fuels, he was struck by its conclusions. Today’s solar cells aren’t efficient enough for widespread use. They also are made of silicon wafers, and like silicon chips, they must be manufactured under expensive high-tech conditions. “The existing solar-cell technologies were off by a very substantial factor from what was really needed,” Alivisatos says. Solar energy needed “someone to come up with a new type of design.”

solar cells that include nanorods
Solar cells that include nanorods.
A rod is a key component of a solar cell, the part that draws and absorbs the sun’s energy. Alivisatos decided that quantum dots’ strong semi-conducting properties—and the fact that they are grown in water—meant that they could be used to make nanoscale rods. To keep the rods properly aligned inside a solar cell so that they absorb solar energy consistently, he and his research team make them in the shape of branching nanocrystals that they call tetrapods. “Imagine a pyramid with all four sides exposed,” Alivisatos says. “We can grow rods out of each face of that pyramid. The result looks like a jack, from the children’s game. It’s a semiconductor that will always stand up on a surface, and should perform more efficiently.”




solar cells that include nanorods
Solar cells that include nanorods.
A rod is a key component of a solar cell, the part that draws and absorbs the sun’s energy. Alivisatos decided that quantum dots’ strong semi-conducting properties—and the fact that they are grown in water—meant that they could be used to make nanoscale rods. To keep the rods properly aligned inside a solar cell so that they absorb solar energy consistently, he and his research team make them in the shape of branching nanocrystals that they call tetrapods. “Imagine a pyramid with all four sides exposed,” Alivisatos says. “We can grow rods out of each face of that pyramid. The result looks like a jack, from the children’s game. It’s a semiconductor that will always stand up on a surface, and should perform more efficiently.”

Next, Alivisatos tackled the question of a cheaper, simpler means of manufacturing solar cells. He came up with a method that “looks much more like the casting of a thin, flexible plastic film than the conventional fabrication of solar cells.” He combines his tetrapods in their solution with plastic, to make solar cells in the form of extremely thin sheets. These sheets can be rolled out like newsprint, “a low-cost, high-volume technique.” They might be ink-jet printed, or even painted onto surfaces like car roofs.

Alivisatos is cofounder of Nanosys, a nanotechnology start up company. Nanosys has secured major funding from Matsushita Electric to market solar roofing tiles using Alivisatos’ design by 2007. This research appeared in the June, 2003 issue of Nature Materials.


 
       email to a friend by Ann Marie Cunningham
               
     


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